姓名:李曼
学历:博士
职称: 副教授
专业方向:理论与计算化学
Email:manli_hx@hust.edu.cn
教育与研究经历
2009-2013, 四川大学 学士
2013-2018, 南开大学, 有机化学专业,博士, 导师: 程津培院士、薛小松研究员
2018-2021, 瑞典斯德哥尔摩大学, 博士后, 导师: Fahmi Himo
2021年至今,44118太阳成城集团,44118太阳成城集团,副教授
研究领域与兴趣
均相有机催化和过渡金属催化理论研究
教学情况
量子化学
承担项目与课题
国家自然科学基金青年项目 2022-2024,主持
湖北省自然科学基金青年项目2021-2023,主持
2021年44118太阳成城集团人才引进基金 2021-2024,主持
代表性成果
1. Xiang Wan, Man Li,* and Rong-Zhen Liao*, Ligand‐assisted Hydride Transfer: A Pivotal Step for CO2 Hydroboration Catalyzed by a Mononuclear Mn (I) PNP Complex. Chem Asian J. 2021, 16, 2529–2537.
2. Man Li, Amparo Sanz-Marco, Samuel Martinez-Erro, Víctor García-Vázquez, Binh Khanh Mai, Jacob Fernández-Gallardo, Fahmi Himo,* and Belén Martín-Matute,* Unraveling the Mechanism of the Ir(III)-Catalyzed Regiospecific Synthesis of α-Chlorocarbonyl Compounds from Allylic Alcohols. Chem. Eur.J.2020, 26,14978–14986.
3. Mingyang Wang#, Man Li#, Shan Yang#, Xiao-Song Xue,* Xinxin Wu, Chen Zhu,* Radical-mediated C-C Cleavage of Unstrained Cycloketones and DFT study for unusual regioselectivity. Nat. Commun. 2020, 11, 1−7. (# : Co-first author)
4. Man Li, Xiao-Song Xue,* and Jin-Pei Cheng, Establishing Cation and Radical Donor Ability Scales of Electrophilic F, CF3, and SCF3 Transfer Reagents. Acc. Chem. Res. 2020, 53, 182−197. (Invited Review)
5. Quan-Qing Zhao, Man Li, Xiao-Song Xue,* Jia-Rong Chen,* and Wen-Jing Xiao,* Visible-Light-Driven Neutral Nitrogen Radical Mediated Intermolecular Styrene Difunctionalization. Org. Lett. 2019, 21, 3861−3865.
6. Jin-Dong Yang,* Man Li, Xiao-Song Xue,* Computational I(III)−X BDEs for Benziodoxol(on)e-based Hypervalent Iodine Reagents: Implications for Their Functional Group Transfer Abilities. Chin. J. Chem. 2019, 37, 359-363. (Invited contribution)
7. Zhengwei Guo, Man Li, Xue-Qing Mou, Gang He,* Xiao-Song Xue,* and Gong Chen,* Radical C−H Arylation of Oxazoles with Aryl Iodides: Dppf as an Electron Transfer Mediator for Cs2CO3. Org. Lett. 2018, 20, 1684-1687.
8. Man Li, Yueqian Sang, Xiao-Song Xue,* and Jin-Pei Cheng, Origin of Stereocontrol in Photoredox Organocatalysis of Asymmetric α-Functionalizations of Aldehydes. J. Org. Chem. 2018, 83, 3333-3338.
9. Man Li, Hanliang Zheng,Xiao-Song Xue,* and Jin-Pei Cheng, Ordering the Relative Power of Electrophilic Fluorinating/Trifluoromethylating/Trifluoromethylthiolating Reagents: A Summary of Recent Efforts. Tetrahedron Lett. 2018, 59, 1278-1285. (Invited Review)
10. Man Li, Xiao-Song Xue,* and Jin-Pei Cheng, Mechanism and Origins of Stereoinduction in Natural Cinchona Alkaloid Catalyzed Asymmetric Electrophilic Trifluoromethylthiolation of β-Ketoesters with N-Trifluoromethylthiophthalimide as Electrophilic SCF3 Source. ACS Catal. 2017, 7, 7977-7986.
11. Man Li#, Biying Zhou#, Xiao-Song Xue,* and Jin-Pei Cheng, Establishing the Trifluoromethylthio Radical Donating Abilities of Electrophilic SCF3‑Transfer Reagents. J. Org. Chem. 2017, 82, 8697-8702. (Featured in J. Org. Chem. spotlight! One of the most read articles in Aug.-Sep. 2017) (# : Co-first author)
12. Man Li, Ya Wang, Xiao-Song Xue,* and Jin-Pei Cheng, A Systematic Assessment of Trifluoromethyl Radical Donor Abilities of Electrophilic Trifluoromethylating Reagents. Asian J. Org. Chem. 2017, 6, 235-240. (Most Accessed Full Paper in 2017).
13. Man Li, Jinping Guo, Xiao-Song Xue,* and Jin-Pei Cheng,* Quantitative Scale for the Trifluoromethylthio Cation-Donating Ability of Electrophilic Trifluoromethylthiolating Reagents. Org. Lett. 2016, 18, 264-267. (Featured in Org. Lett. spotlight! One of the most read articles in Jan.-Feb. & Highly Cited Paper in 2016)
14. Man Li, Xiao-Song Xue,* Jinping Guo, Ya Wang, and Jin-Pei Cheng,* An Energetic Guide for Estimating Trifluoromethyl Cation Donor Abilities of Electrophilic Trifluoromethylating Reagents: Computations of X−CF3 Bond Heterolytic Dissociation Enthalpies. J. Org. Chem. 2016, 81, 3119-3126. (One of the most read articles in Mar.-Apr. 2016)
15. Panpan Zhang, Man Li, Xiao-Song Xue,* Chunfa Xu, Qunchao Zhao, Yafei Liu, Haoyang Wang, Yinlong Guo, Long Lu,* and Qilong Shen,* N-Trifluoromethylthio-dibenzenesulfonimide: A Shelf-Stable, Broadly Applicable Electrophilic Trifluoromethylthiolating Reagent. J. Org. Chem. 2016, 81, 7486-7509. (One of the most read articles in Jul.-Aug. 2016 & Highly Cited Paper in 2017)